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Transport of trivalent lanthanides in a H2O-CHCl3H2O liquid membrane system containing a crown ether carboxylic acid
Institution:1. CAS Key Laboratory of Mechanical Behavior and Design of Materials, Department of Modern Mechanics, University of Science and Technology of China, Hefei, 230027, China;2. Faculty of Mechanical & Material Engineering, Huaiyin Institute of Technology, Huai''an, Jiangsu, 223003, China;3. College of Civil Engineering, Nanjing Tech University, Nanjing, Jiangsu, 211816, China;1. Department of Geology, Faculty of Science, University of Peradeniya, Peradeniya, Sri Lanka;2. Postgraduate Institute of Science, University of Peradeniya, Peradeniya, Sri Lanka;3. National Water Supply and Drainage Board, Telewala Road, Ratmalana, Sri Lanka;1. MOE Key Laboratory of Groundwater Circulation and Environmental Evolution, School of Water Resources and Environment, China University of Geosciences (Beijing), Beijing 100083, PR China;2. Beijing Key Laboratory of Water Resources and Environmental Engineering, School of Water Resources and Environment, China University of Geosciences (Beijing), Beijing 100083, PR China;3. Hangzhou Yanqu Information Technology Co., Ltd., Hangzhou City, Zhejiang Province 310003, PR China
Abstract:Neutral crown ethers do not transport trivalent lanthanide cations in a H2O-CHCl3-H2O liquid membrane system. With the addition of a carboxylate group to a macrocyclic polyether, as in the case of sym-dibenzo-16-crown-5-oxyacetic acid, high efficiencies of transporting trivalent lanthanides were observed across the H2O-CHCl3-H2O liquid membrane. The crown ether carboxylic acid also showed significant selectivity for the lanthanides studied in this system.
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