Synthesis of a new chiral nitrogen containing diselenide as a precursor for selenium electrophiles |
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| Institution: | 1. Istituto di Chimica Organica Università degli Studi, I-06123 Perugia, Italy;2. Institut für Organische Chemie der Universität Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland;1. Faculty of Chemistry, Maria Curie-Sklodowska University, 20-031 Lublin, Poland;2. Department of Biochemistry, Medical University of Warsaw, Warszawa 02-097, Poland;3. Department of Pharmacogenomics, Medical University of Warsaw, 02-007 Warszawa, Poland;1. School of Pharmacy, University of Otago, Dunedin, New Zealand;2. Department of Pharmacology and Toxicology, Otago School of Medical Sciences, University of Otago, Dunedin, New Zealand;1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar, 388 120, Gujarat, India;2. Department of Chemical Sciences, P. D. Patel Institute of Applied Sciences, Charotar University of Science and Technology (CHARUSAT), Changa, 388 421, Gujarat, India;3. Theory Group, Max Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany;4. Shri A. N. Patel P. G. Institute of Science & Research, Anand, 388001, Gujarat, India;5. M. B. Patel Science College, Anand, 388001, Gujarat, India |
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| Abstract: | The synthesis of a new chiral nitrogen containing diselenide is described starting from (1S,2S)-1,2-diphenylethylendiamine. The electrophilic selenium species generated from this diselenide have been used for methoxyselenenylation reactions at room temperature with good yields and high diasteroselectivities. |
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