Lipase-mediated kinetic resolution of a synthetic equivalent of 2-hydroxymethylcyclopentadien-5-ol |
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| Affiliation: | 1. College of Advanced Interdisciplinary Science and Technology, Henan University of Technology, Zhengzhou 450001, China;2. Division of Chemistry and Biological Chemistry, School of Chemistry Chemical Engineering, and Biotechnology, Nanyang Technological University, Singapore 637371, Singapore;3. Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering Nanjing Tech University, Nanjing 211816, China;4. State Key Laboratory of Applied Organic Chemistry, Department of Chemistry, Lanzhou University, Lanzhou 730000, China |
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| Abstract: | Racemic 3-hydroxy-2-hydroxymethyl-endo-tricyclo[5.2.1.02,6]-dec-4,8-diene serving as a synthetic equivalent of 2-hydroxymethylcyclopentadien-5-ol has been resolved by employing lipase-mediated kinetic transesterification with vinyl acetate in an organic solvent. |
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