New 1,10-phenanthroline ligands for asymmetric catalysis: enantioselective palladium catalyzed allylic substitution |
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| Affiliation: | 1. Department of biomedical Engineering, Military Technical College, Kobry Elkoba, Cairo, Egypt;2. Nanotechnology Center, Military Technical College, Kobry El-Kobba, Cairo, Egypt |
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| Abstract: | A number of new chiral C1-symmetric 1,10-phenathrolines have been prepared and assessed in the enantioselective palladium catalyzed allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethylmalonate. Enantioselectivities up to 84% were obtained. |
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