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Stereoselective cis-dihydroxylation of azulene and related non-aromatic polyenes
Institution:1. School of Chemistry, The Queen''s University of Belfast, Belfast BT9 5AG, UK;2. QUESTOR Centre, The Queen''s University of Belfast, Belfast BT9 5AG, UK;3. Department of Biological Sciences, University of Warwick, Coventry CV4 7AL, UK;1. Department of Chemistry, and Key Laboratory of Guizhou High Performance Computational Chemistry, Guizhou University, Guiyang 550025, China;2. College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang 471934, China
Abstract:Dioxygenase-catalysed dihydroxylation of azulene and related non-aromatic polyenes has been found to yield enantiopure chiral cis-diols of synthetic potential.
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