Synthesis of chiral epoxyalkynes |
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| Institution: | 1. Institute of Chemistry at Tallinn Technical University, Akadeemia tee 15, EE0026 Tallinn, Estonia;2. Institute of Chemical Physics and Biophysics, Akadeemia tee 23, EE0026 Tallinn, Estonia;1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China;2. Zhejiang Base of National Southern Pesticide Research Centre, Zhejiang Research Institute of Chemical Industry, Hangzhou 310023, China;1. School of Pharmacy, East China University of Science & Technology, Shanghai 200237, China;2. Shandong Keyuan Pharmaceutical Co., Ltd., Shandong Shanghe Economic Development Zone, Jinan 251601, China;1. School of Studies in Chemistry, Jiwaji University, Gwalior, 474011, India;2. Department of Chemistry, Islamic University of Science and Technology, Awantipora, Kashmir, 192122, India;3. Govt Degree College Khanabal, Anantnag, Kashmir, 192101, India;4. Department of Chemistry, Howard University, Washington, DC, 20059, USA;1. D. Mendeleev University of Chemical Technology of Russia, Miusskaya Sq. 9, 125047, Moscow, Russia;2. Enikolopov Institute of Synthetic Polymeric Materials, A Foundation of the Russian Academy of Sciences, Profsoyuznaya St. 70117393, Moscow, Russia |
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| Abstract: | The synthesis of novel chiral propargylic epoxides ((R)-1-t-butyldimethylsilyl-3,4-epoxy-1-butyne, (3S,4S)-3,4-epoxy-1-octyne, (3R,4S)-1-t-butyldimethylsilyl-3,4-epoxy-1-pentyne) has been developed starting from the readily available tartaric acid derivative, (S,S)-(+)-2,3-O-isopropylidene-L-threitol. |
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