| 致密度对填充skutterudite化合物La0.75Fe3CoSb12热电性能的影响 |
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| 引用本文： | 杨 磊,张澜庭,吴建生. 致密度对填充skutterudite化合物La0.75Fe3CoSb12热电性能的影响[J]. 物理学报, 2004, 53(2): 537-542 |
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| 作者姓名： | 杨 磊 张澜庭 吴建生 |
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| 作者单位： | 上海交通大学材料科学与工程学院教育部高温材料及测试开放实验室,上海 200030 |
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| 基金项目： | 国家自然科学基金（批准号：59902003）资助的课题. |
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| 摘 要： | 研究了致密度对填充skutterudite化合物La0.75Fe3CoSb12热电性能的影响.La0.75Fe3CoSb12表现为p型传导，载流子迁移率随着致密度的增加而升高.由于样品中空洞的散射作用，致使电阻率ρ随着致密度的降低而升高，同时造成热导率κ的下降，但塞贝克系数α与致密度关系不大，致密度造成电阻率ρ升高的比率与热导率κ下降的比率相当，致密度不同的样品具有相当的ZT关键词：致密度填充式skutterudite化合物热电性能
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| 关 键 词： | 致密度 填充式skutterudite化合物 热电性能 |
| 收稿时间： | 2003-01-14 |
Effect of density on the thermoelectric properties of the filled skutterudite compound La0.75Fe3CoSb12 |
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| Yang Lei,Zhang Lan-Ting and Wu Jian-Sheng. Effect of density on the thermoelectric properties of the filled skutterudite compound La0.75Fe3CoSb12[J]. Acta Physica Sinica, 2004, 53(2): 537-542 |
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| Authors: | Yang Lei Zhang Lan-Ting Wu Jian-Sheng |
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| Abstract: | The effect of density on the thermoelectric properties of the filled skutterudite compound La0.75Fe3CoSb12 was investigated. The La0.75Fe3CoSb12 showed p-type conduction. The mobility increased with an increase in density. The electrical resistivity increased and the thermal conductivity decreased with decreasing density due to the pores scattering. The Seebeck coefficient is independent of density. The portion of electrical resistivity increase is consistent with that of the thermal conductivity reduction. The value of ZT of the specimen with low density is compared to that of specimen with high density. The value of ZT does not depend on density. |
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| Keywords: | denseness filled skutterudite compound thermoelectric properties |
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