| Novel Chiral Ferrocenyl Aziridino Alcohol Catalysts Promoting Asymmetric Addition of Diethylzinc to Aldehydes |
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| 引用本文： | 王敏灿 王德坤 娄建平 华远照. Novel Chiral Ferrocenyl Aziridino Alcohol Catalysts Promoting Asymmetric Addition of Diethylzinc to Aldehydes[J]. 中国化学, 2004, 22(6): 512-514. DOI: 10.1002/cjoc.20040220604 |
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| 作者姓名： | 王敏灿 王德坤 娄建平 华远照 |
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| 作者单位： | DepartmentofChemistry,ZhengzhouUniversity,Zhengzhou,Henan450052,China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China (No. 20172047)，Henan Outstanding Youth Program 2001，and the Education Department of Henan Province. |
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| 摘 要： | Optically active aziridino alcohols containing ferrocenyl groups were prepared from commercially available L-threonine in excellent yields and used as catalysts to promote the asymmetric addition of diethylzinc to aryaldehydes to afford 1-arylpropanol in up to 84% enantiomeric excesses with moderate to good yields.
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| 关 键 词： | 二茂铁基 醇 乙醛 二乙基锌 不对称加成 催化反应 L-苏氨酸 Aziridino |
Novel Chiral Ferrocenyl Aziridino Alcohol Catalysts Promoting Asymmetric Addition of Diethylzinc to Aldehydes |
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| WANG,Min-Can WANG,De-Kun LOU,Jian-PingHUA,Yuan-Zhao. Novel Chiral Ferrocenyl Aziridino Alcohol Catalysts Promoting Asymmetric Addition of Diethylzinc to Aldehydes[J]. Chinese Journal of Chemistry, 2004, 22(6): 512-514. DOI: 10.1002/cjoc.20040220604 |
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| Authors: | WANG Min-Can WANG De-Kun LOU Jian-PingHUA Yuan-Zhao |
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| Affiliation: | WANG,Min-Can WANG,De-Kun* LOU,Jian-PingHUA,Yuan-ZhaoDepartment of Chemistry,Zhengzhou University,Zhengzhou,Henan 450052,China |
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| Abstract: | Optically active aziridino alcohols containing ferrocenyl groups were prepared from commercially available L-threonine in excellent yields and used as catalysts to promote the asymmetric addition of diethylzinc to aryalde-hydes to afford 1-arylpropanol in up to 84% enantiomeric excesses with moderate to good yields. |
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| Keywords: | ferrocenyl aziridino alcohol catalyst asymmetric addition |
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