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Novel structurally characterized o-semiquinonato PCP-pincer nickel complexes
Authors:Konstantin A. Kozhanov   Michael P. Bubnov   Nina N. Vavilina   Larisa Yu. Efremova   Georgy K. Fukin   Vladimir K. Cherkasov  Gleb A. Abakumov
Affiliation:aG.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603950 Nizhny Novgorod, Russia
Abstract:Structural study of dialkyl (PCP)-pincer o-semiquinonato nickel complexes indicated sloped relative positions of bi- and tri-dentate ligands. It became bright confirmation of propositions made on the base of their EPR spectra followed by molecular modelling.
Keywords:Pincer complexes   o-Semiquinones   Nickel   X-ray diffraction
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