CRYSTAL STRUCTURE AND CALCULATION OF SECOND ORDER POLARIZABILITY OF [Cd(NH_2CSNHNH_2)Br_2]·H_2O |
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基金项目: | The Project supported by National Natural Sciences Foundation of China |
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摘 要: | <正> Cd(NH2CSNHNH2) Br2]· H2O is a new nonlinear optical organometallic complex, and the single crystal structural analysis has been carried out by X-ray diffraction method. According to the model of the second order polarizabili-ty vector, the second order polarizability of one dimensional doubling frequency group of the title compound was calculated using the structural data and the second harmonic relative intensity I2ω/I2ω,KDP.
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CRYSTAL STRUCTURE AND CALCULATION OF SECOND ORDER POLARIZABILITY OF [Cd(NH_2CSNHNH_2)Br_2]·H_2O |
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Abstract: | Cd(NH2CSNHNH2) Br2]· H2O is a new nonlinear optical organometallic complex, and the single crystal structural analysis has been carried out by X-ray diffraction method. According to the model of the second order polarizabili-ty vector, the second order polarizability of one dimensional doubling frequency group of the title compound was calculated using the structural data and the second harmonic relative intensity I2ω/I2ω,KDP. |
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