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Determination of selenium in infant foods using electrothermal atomic absorption spectrometry with direct slurry sample introduction
Authors:Baralkiewicz  Danuta  El-Sayed  Usama  Filipiak  Marian  Gramowska  Hanka  Mleczek  Miroslaw
Institution:(1) Faculty of Chemistry, Adam Mickiewicz, University, Drzymaly 24, 60-613 Poznan, Poland;(2) Biochemistry and Microbiology, Poznan University of Economics, Al. Niepodleglosci 10, 60-967 Poznan, Poland
Abstract:Slurry sampling electrothermal atomic absorption (SS ETAAS) was applied to the development of a sensitive and precise method for selenium determination in infant foods without sample pretreatment. Suspensions prepared in a medium containing 0.1% Triton X-100, 0.5 or 5% v/v concentrated HNO3 were directly introduced into the furnace. The accuracy of the procedure was confirmed by analysis of a standard reference material and comparison with hydride generation atomic absorption spectrometric (HGAAS) procedure. The characteristic mass is 44 pg and detection limit 0.43 μg·l−1.
Keywords:selenium                      infant foods                      slurry sampling atomic absorption spectrometry (SS ETAAS)
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