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Electrocatalytic Oxidation of Hypophosphite on Nickel Electrode ──In Situ UV-Vis Spectroscopic study
作者姓名:Yue ZENG  Shao Min ZHOU
作者单位:Department of Chemistry. Hunan Normal University,Changsha 410006 State Key Laboratory for Physical Chemistry of the Solid Surface.Department of Chemistry. Xiamen University,Xiamen 361005
摘    要:ThefactthathypophosphiteisoneofthemostwidelyusedreducingagentsintheNielectrolessdepositionhasstimulatedthestudyofanodicoxidationofhypophosphiteonnicked-ic.Thisanodicreaction,whichisimportantfortheunderstandingoftheNielectrolessdepositionmechanism,isexpectedtobeoneoftheimportantreactionsintheNi-electrolessprocess.Recently,theroleandoxidationmechanismofhypophosphiteinelectrolessdepositionofNi-Palloyhavebeenstudiedindetailusingtheprobebeamdeflection',electrochemistryandinsituIR',lo.However,som…

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