Peculiarities in oxidative conversion of methane to C2 hydrocarbons over CaO?CaCl2 catalysts |
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| Authors: | A N Shigapov M A Novoshilova S N Vereshchagin A G Anshits and V D Sokolovskii |
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| Institution: | (1) Institute of Chemistry and Chemical Technology, 660049 Krasnoyarsk;(2) Institute of Catalysis, 30090 Novosibirsk, USSR |
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| Abstract: | Experimental data for the oxidative dimerization of methane over CaO–CaCl2 systems indicate that C2 hydrocarbons are formed with the participation of chlorine generated by the catalyst surface under the effect of a reaction medium. A heterogeneous-homogeneous scheme for this process is suggested.
                  CaO–CaCl2    ,   C2-  ,   .   - .
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