Kinetics and mechanism of the reaction of 1-chloro-2,4,6-trinitrobenzene with the N,N-dimethylaminohydrazone of furfural in acetonitrile |
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| Authors: | G. D. Titskii S. P. Ivonin T. S. Gaidash M. V. Voevudskii |
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| Affiliation: | (1) L. M. Litvinenko Institute of Physicoorganic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Luxemburg ul., 83114 Donetsk, Ukraine;(2) Dnepropetrovsk State University, 13 Nauchnyi Prospekt, 320625 Dnepropetrovsk, Ukraine |
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| Abstract: | Kinetics of the arylation of the N,N-dimethylaminohydrazone of furfural with picryl chloride in acetonitrile at 298 K has been studied. The reaction is not catalyzed by nucleophiles. The mechanism includes the rapid equilibrium formation of σ-adduct with its slow unimolecular decomposition. Rate and equilibrium constants for the individual steps were calculated. Translated from Teoreticheskaya i éksperimental'naya Khimiya, Vol. 36, No. 3, pp. 173–176, May–June, 2000. |
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