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Steric specificity of the direct13C-1H spin-spin coupling constants in the vinyl group in N-vinylpyrroles
Authors:A. V. Afonin  M. V. Sigalov  V. K. Voronov  E. Yu. Shmidt  B. A. Trofimov
Affiliation:(1) Institute of Organic Chemistry, Siberian Division, Academy of Sciences of the USSR, Irkutsk
Abstract:Conclusions The direct13C-1H spin-spin coupling constants of the vinyl group beta-carbon in N-vinyl-pyrroles display steric specificity and change depending on the dihedral angle between the planes of the vinyl group and the heterocycle.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1418–1421, June, 1987.
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