| 绝热式热动力学的研究I:可逆反应动力学的数学模型 |
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| 引用本文： | 邓郁,杨明利.绝热式热动力学的研究I:可逆反应动力学的数学模型[J].化学学报,1987,45(2):120-126. |
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| 作者姓名： | 邓郁 杨明利 |
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| 作者单位： | 四川大学化学系 |
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| 摘 要： | 本文提出了几类可逆反应通用的微分动力学方程.并应用无量纲参数法,建立了可逆反应动力学的数学模型.还给出了一个解析实例.
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| 关 键 词： | 速率 计算 反应动力学 数学模型 热力学 平衡常数 动力学方程 可逆过程 无量纲数 |
Studies on adiabatic thermokinetics I: Mathematical models of reversible reaction kinetics |
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| DENG YU,YANG MINGLI.Studies on adiabatic thermokinetics I: Mathematical models of reversible reaction kinetics[J].Acta Chimica Sinica,1987,45(2):120-126. |
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| Authors: | DENG YU YANG MINGLI |
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| Abstract: | A general differential kinetics equation for several kinds of reversible reactions is proposed. By combining this equation with dimensionless parameters, some math. models of reversible reaction kinetics are suggested, which are used for calculating both rate and equilibrium constants An application of the models is given and the results are in agreement with those in the literature. The math. models of first-order and second-order reaction kinetics are also derived as specific examples of the application of this approach.6 |
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| Keywords: | RATE CALCULATION REACTION KINETICS MATHEMATICAL MODELS THERMODYNAMICS EQUILIBRIUM CONSTANT KINETICS EQUATIONS REVERSIBLE PROCESS DIMEN |
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