Abstract: | Polynuclear Cobalt Complexes: The Structure of Bis(tri-μ-hydroxo-bis{triammine-cobalt(III)})trisdithionate The binuclear complex (NH3)3Co · μ(OH, OH, OH) · Co(NH3)3]2(S2O6)3 crystallizes in the monoclinic space group P21/c with lattice constants a = 10.970, b = 9.412, c = 16.069 Å and β = 117.10°. The unit cell contains four cations and six anions. The structure has been determined by an X-ray crystallographic analysis and was refined to R = 0.052. |