| AlCl3催化作用下苯胺与CS2的反应机理初探 |
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| 引用本文： | 袁新华,倪中海,熊玉春,宗志敏,魏贤勇.AlCl3催化作用下苯胺与CS2的反应机理初探[J].化学通报,2002,65(9):627-630. |
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| 作者姓名： | 袁新华 倪中海 熊玉春 宗志敏 魏贤勇 |
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| 作者单位： | [1]江苏大学材料学院，江苏镇江212013 [2]中国矿业大学化学化工学院，江苏徐州221008 |
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| 基金项目： | 江苏大学高级人才基金(6810000019) |
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| 摘 要： | 二苯硫脲是重要的医药和染料的中间体。常温常压下，用AlCl3作催化剂催化苯胺和CS2进行反应，可以高收率和高选择性地得到二苯硫脲。反应产物经GC／MS进行了检测，并提出了AlCl3催化苯胺和CS2的可能反应机理。
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| 关 键 词： | AlCl3 催化作用 苯胺 CS2 二苯硫脲 三氯化铝 反应机理 GC／MS 催化剂 二硫化碳 |
| 修稿时间： | 2002年1月4日 |
Study on the Mechanism of Reaction of Aniline with CS2 over AlCl3 Catalyst |
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| Yuan Xinhua,Ni Zhonghai,Xiong Yuchun,Zong Zhimin,Wei Xianyong.Study on the Mechanism of Reaction of Aniline with CS2 over AlCl3 Catalyst[J].Chemistry,2002,65(9):627-630. |
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| Authors: | Yuan Xinhua Ni Zhonghai Xiong Yuchun Zong Zhimin Wei Xianyong |
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| Abstract: | Diphenyl thiourea is an important intermediate of medicine and dyestuff. Under mild conditions, at room temperature and ambient atmosphere, diphenyl thiourea could be synthesized through the reaction of aniline and CS 2 over AlCl 3 catalyst with high yield and high selectivity. The reaction product were identified by GC/MS and reasonable mechanism of the reaction was also discussed. |
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| Keywords: | Diphenyl thiourea AlCl 3 Reaction mechanism GC/MS |
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