Separation of Zr in the rubble waste generated at the Fukushima Daiichi Nuclear Power Station |
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Authors: | Asako Shimada Yutaka Kameo |
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Affiliation: | 1.Department of Decommissioning and Waste Management,Japan Atomic Energy Agency,Naka-gun,Japan;2.International Research Institute for Nuclear Decommissioning,Tokyo,Japan |
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Abstract: | Separation method of Zr using trans uranium resin (TRU resin) and tetra valent actinide resin (TEVA resin) was developed for the analysis of 93Zr contained in the rubble waste. Zr, Nb, and U were quantitatively extracted on the TRU resin from 3 M HNO3 and striped with 0.01 M HF, in addition, some part of Mo, Hg, Bi, and Th were also included in the stripping solution. The stripping solution was evaporated to eliminate HNO3 and the residue was dissolved in 0.1 M HF. Finally, Zr was separated from Nb and Mo with the TEVA resin. |
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