| Abstract: | μ‐Phthalocyaninato‐bis({triphenylphosphine oxide}sodium): Synthesis and Crystal Structure Blue μ‐phthalocyaninato‐bis({triphenylphosphine oxide}sodium) ( 1 ) is prepared by heating triphenylphosphine oxide with disodium phthalocyaninate at 160 °C. 1 is centrosymmetric (space group P1). The Na atom is located in a tetragonal pyramid co‐ordinating four isoindole N atoms at a distance varying between 2.409(2) and 2.438(2) Å, and one O atom at 2.198(2) Å. The Na–Na distance is 2.823(5) Å, and the Na–O–P angle is 145.5(1)°. |
