Abstract: | A new decoration method termed as focal‐conic texture decoration has been established to map the director field of disclinations of nematic mesophases for a side‐chain liquid crystalline polymer (SCLCP) based on its transition from nematic to smectic phase with focal‐conic texture observed under a polarizing optical microscope. FT‐IR microscopy was used to ascertain the relationship between the mesogenic orientation direction and the orientation direction of focal‐conic texture, which exhibits consequently the director field of a disclination. |