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Effective χ and surface segregation in blends of star and linear polystyrene
Authors:Mark D. Foster  Carmen C. Greenberg  David M. Teale  C. Michele Turner  Sergio Corona‐Galvan  Eric Cloutet  Paul D. Butler  Boualem Hammouda  Roderic P. Quirk
Abstract:The existence in blends of linear and star branched polystyrenes (PS) of a bulk thermodynamic interaction due to differences in macromolecular architecture has been demonstrated with small angle neutron scattering measurements. It has also been demonstrated that a regularly star‐branched polystyrene material segregates preferentially to the surface of a blend of star and linear molecules.
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