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Electron transfer of conjugated polymeric ferrocenes
Authors:Masato Kurihara  Kenya Kubo  Tesuo Horikoshi  Masaru Kurosawa  Takuya Nankawa  Takayuki Matsuda  Hiroshi Nishihara
Abstract:This paper describes three topics on the π‐conjugated ferrocene oligomers and polymers; the first is the dependence of intervalence‐transfer bands for mixed‐valence oligo(1,1'‐dihexylferrocenylene)s on the oxidation number and the number of ferrocene units, the second is synthesis of azo‐bridged ferrocene oligomers and a polymer and electrochemical and optical analysis of internuclear electronic interactions in their mixed‐valence states and the third is synthesis, redox behaviors and electrodeposition of oligoferrocenylene‐modified gold clusters.
Keywords:
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