Crystal Structure of the Amine‐Carbonato‐Cobalt(III) Complex [Co(CO3)(L1)]ClO4 with Aminoalkyl Pendant‐Arm [12]eneN4, L1 = 9‐(3‐aminopropyl)‐1,5,9‐Triazacyclododecene |
| |
| Authors: | SS Massoud FA Mautner MAM Abu‐Youssef |
| |
| Abstract: | The crystal and molecular structure of the title complex Co(CO3)(L1)]ClO4 was determined from X‐ray diffraction data using direct methods. The crystals are monoclinic, a = 13.588(4) Å, b = 9.049(3) Å, c = 15.569(6) Å, β = 114.75(2)°, Z = 4, V = 1738.5(10) Å3, space group P21/n. The structure consists of isolated Co(CO3)(C12H26N4)]+ complex cations, with distorted octahedral geometry and ClO4‐ counter anions. The results are discussed in relation to similar macrocycle and carbonato analogues. |
| |
| Keywords: | crystal structure Cobalt(III) complexes carbonato complexes azido complexes tetrammin ligand macrocycle |
|
|
