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Struktur von Hexafulminatocobaltat(III), [Co(CNO)6]3–
Authors:Peter Mayer  Walter Ponikwar  Klaus Feldl  Peter Swoboda  Wolfgang Beck
Abstract:Pseudohalogeno Metal Compounds. LXXVII. Structure of Hexafulminatocobaltate(III), Co(CNO)6]3– In the crystal of AsPh4]3Co(CNO)6] the hexafulminatocobaltate(III) anion forms an ideal octahedron with linear C≡N–O ligands and with relatively short cobalt‐carbon bonds (Co–C 191 pm). In the crystal the AsPh4]+ cations “dilute” the energy rich anions.
Keywords:Cobalt  Fulminates  Crystal structure
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