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Size-independent peak shift between normal and upconversion photoluminescence in MPA-capped CdTe nanoparticles
Authors:S ANANTHAKUMAR  J JAYABALAN  ASHA SINGH  SALAHUDDIN KHAN  SUBHASH PRAJAPATI  S MOORTHY BABU  RAMA CHARI
Affiliation:1. Crystal Growth Centre, Anna University, Chennai, 600 025, India
2. Laser Physics Applications Section, Raja Ramanna Centre for Advanced Technology, Indore, 452 013, India
Abstract:In this article, we report size-dependent measurement of the shift in peak of upconversion photoluminescence spectra compared to that of normal photoluminescence using a 800 nm femtosecond laser and its second harmonic. It has been shown that the upconversion photoluminescence is always red-shifted compared to that of normal PL in all the samples. By measuring the power-dependent upconversion photoluminescence (UCPL), it has been shown that the origin of UCPL from MPA-capped CdTe nanoparticles is mainly of two-photon absorption
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