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Crystal structure of [Pd(NH3)4][Rh(NH3)(NO2)5] |
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| Authors: | E A Shusharina A A Rybinskaya P E Plyusnin Yu V Shubin S V Korenev and S A Gromilov |
| Abstract: | An XRD analysis is used to study the single crystal of Pd(NH3)4]Rh(NH3)(NO2)5] double complex salt at T = 150(2) K. Crystallographic characteristics are as follows: a = 7.6458(5) ?, b = 9.8813(6) ?, c = 9.5788(7) ?, β = 109.469(2)°, V = 682.30(8) ?3, P21/m space group, Z = 2, d x = 2.553 g/cm3. The geometry of the complex Rh(NH3)(NO2)5]2− anion is described for the first time: Rh-N(NO2) distances are 2.020(4)–2.060(3) ?, Rh-N(NH3) 2.074(4) ?, N(NO2)-Rh-N(NH3) trans-angle is 178.8(2)°. |
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