Formal synthesis of (+/-)-dendrobine: use of the amidofuran cycloaddition/rearrangement sequence |
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Authors: | Padwa A Dimitroff M Liu B |
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Institution: | Department of Chemistry, Emory University, Atlanta, Georgia 30322, USA.chemap@emory.edu |
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Abstract: | The formal synthesis of the alkaloid (+/-)-dendrobine (4) was accomplished using the IMDAF cycloaddition/rearrangement sequence of a furanyl carbamate. Conversion of the rearranged cycloadduct to Kende's advanced intermediate in eight steps completed the formal synthesis of (+/-)-dendrobine. |
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