Rhodium-catalyzed addition/ring-opening reaction of arylboronic acids with cyclobutanones |
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| Authors: | Matsuda Takanori Makino Masaomi Murakami Masahiro |
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| Institution: | Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan. |
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| Abstract: | Cyclobutanones react with arylboronic acids in the presence of a catalytic amount of Rh(I) complex to afford butyrophenone derivatives through the addition of an arylrhodium(I) species to the carbonyl group, followed by ring-opening of the resulting rhodium(I) cyclobutanolate. reaction: see text] |
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