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Effect of polyfunctional monomers on properties of radiation crosslinked EPDM/waste tire dust blend
Authors:Tariq Yasin  Sajid Khan  Young-Chang NhoRashid Ahmad
Affiliation:a Department of Metallurgy and Materials Engineering, Pakistan Institute of Engineering and Applied Sciences, P.O. Nilore, PO Box 45650, Islamabad, Pakistan
b Department of Chemistry, Hazara University, Mansehra, Pakistan
c Radiation Research Division of Industry and Environment, Korea Atomic Energy Research Institute, Jeongeup-si, Jeollabuk-do, 580-185, Korea
Abstract:In this study, waste tire dust is recycled as filler and blended with ethylene-propylene diene monomer (EPDM) rubber. Three different polyfuntional monomers (PFMs) are incorporated into the standard formulation and irradiated under electron beam at different doses up to maximum of 100 kGy. The combined effects of PFMs and absorbed dose on the physical properties of EPDM/WTD blend are measured and compared with sulfur crosslinked formulation. Thermogravimetric analysis showed that radiation developed better crosslinked network with higher thermal stability than sulfur crosslinked structure. The physical properties of radiation crosslinked blend are similar to the sulfur crosslinked blend. The absence of toxic chemicals/additives in radiation crosslinked blends made them an ideal candidate for many applications such as roof sealing sheets, water retention pond, playground mat, sealing profile for windows etc.
Keywords:Radiation crosslinking   Waste tire dust   Recycling   EPDM   Polyfuntional monomer
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