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Fabrication of ZnO nanorods in ionic liquids and their photoluminescent properties
作者单位:WANG Li(College of Chemistry, Nankai University, Tianjin 300071, China) ; ZHAO Bin(College of Chemistry, Nankai University, Tianjin 300071, China) ; CHANG LiXian(College of Chemistry, Nankai University, Tianjin 300071, China) ; ZHENG WenJun(College of Chemistry, Nankai University, Tianjin 300071, China) ;
基金项目:国家自然科学基金;国家重点基础研究发展计划(973计划)
摘    要:A novel and simple approach is reported to fabricate uniform single-crystal ZnO nanorods in ionic liq-uids. The as-obtained ZnO nanorods have been characterized by XRD,TEM,HRTEM,SAED,XPS,EDXA,PL and UV-vis absorption spectra. The rod diameters of the nanostructures can be controlled by tuning the amount of sodium hydroxide in the synthesis. Photoluminescence results show that the nanos-tructural ZnO exhibits better optical properties than bulk ZnO does and interestingly,the smaller the rod diameters are,the better optical property 1D nanostructural ZnO exhibits. The possible growth mechanism of ZnO nanorods is also investigated.

收稿时间:3 July 2006
修稿时间:7 September 2006

Fabrication of ZnO nanorods in ionic liquids and their photoluminescent properties
Authors:Wang Li  Zhao Bin  Chang LiXian  Zheng WenJun
Institution:College of Chemistry, Nankai University, Tianjin 300071, China
Abstract:A novel and simple approach is reported to fabricate uniform single-crystal ZnO nanorods in ionic liq-uids. The as-obtained ZnO nanorods have been characterized by XRD,TEM,HRTEM,SAED,XPS,EDXA,PL and UV-vis absorption spectra. The rod diameters of the nanostructures can be controlled by tuning the amount of sodium hydroxide in the synthesis. Photoluminescence results show that the nanos-tructural ZnO exhibits better optical properties than bulk ZnO does and interestingly,the smaller the rod diameters are,the better optical property 1D nanostructural ZnO exhibits. The possible growth mechanism of ZnO nanorods is also investigated.
Keywords:zinc oxide  nanorods  low-heating solid-state route  ionic liquids
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