A guest-induced reversible switching of a self-assembled H-bonded supramolecular framework |
| |
Authors: | Mobian Pierre Huguenard Clarisse Henry Marc |
| |
Institution: | Laboratoire de Chimie Moléculaire de l'Etat Solide, UMR 7140, Université de Strasbourg, 67070 Strasbourg, France. mobian@unistra.fr henry@unistra.fr |
| |
Abstract: | A new class of organic crystalline 2,2'-biphenol-based H-bonded material displaying 1D-channels encapsulating solvent molecules is described. A reversible guest-induced crystal-to-crystal conversion between the solvated H-bonded phase and a compact H-bonded non-solvated phase was observed. The energy competition between intramolecular H-bonds formation and solvation of organic pores has been characterized using PACHA calculations. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|