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Utilization of Carbon Paste Electrodes for the Voltammetric Determination of Chlortoluron
Authors:Hana Dejmkova  Lucie Houskova  Jiri Barek  Jiri Zima
Affiliation:Charles University in Prague, Faculty of Science, Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, Albertov 6, CZ‐12843 Prague 2, Czech Republic
Abstract:Conventional (CPE) and miniaturized (m‐CPE) carbon paste electrodes consisting of a carbon paste filled capillary were used for differential pulse voltammetric determination of chlortoluron in samples of river water and soil, in the latter case after the extraction by methanol. Britton‐Robinson buffer pH 3 with low content of methanol was found to be optimal for the determination. The achieved determination limits were 2.8 µmol L?1 and 0.34 µmol L?1 in river water, and 3.1 and 4.3 µg g?1 in soil, using CPE and m‐CPE, respectively.
Keywords:Pesticides  Differential pulse voltammetry  Miniaturized carbon paste electrodes  Soil  Surface water
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