Novel Tin Complexes Containing an Oximato Ligand: Synthesis,Characterization, and Computational Investigation |
| |
| Authors: | Raji Thomas Joseph P Nelson Ramchand T Pardasani Pushpa Pardasani Tulsi Mukherjee |
| |
| Institution: | 1. Department of Chemistry, University of Rajasthan, Jaipur‐302055, India;2. Department of Chemistry, Central University of Rajasthan, Bandarsindri, Ajmer‐305802, India;3. Chemistry Division, BARC, Mumbai‐400085, India |
| |
| Abstract: | Organotin complexes 1 – 6 of the general formula SnR2L] and (SnR3)2L] (L=phenanthrenequinone dioximato – a bidentate ligand, R=Me, Bu, and Ph) were synthesized by the reaction of the sodium salt of the ligand H2L (prepared in situ with MeONa) and SnR2Cl2/SnR3Cl in 1 : 1 and 1 : 2 molar ratios. The physical and spectral properties of the newly synthesized complexes 1 – 6 are described. DFT and HF Calculations were performed to confirm the proposed structures. |
| |
| Keywords: | Organotin oximates Tin complexes Density‐functional theory (DFT) |
|
|
