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Photolysis of Dibenzo[a,d]cycloheptene Dimer
Authors:Meng‐Yang Chang  Yu‐Ping Huang
Affiliation:Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, Kaohsiung 807, Taiwan, R.O.C.
Abstract:Photolysis reaction of dibenzo[a,d]cycloheptene dimer 3 provides three dibenzo[a,d]cycloheptyl dimers 4 , 5 and 6 under different irradiation conditions via the intramolecular degradative cyclodimerization. A tetracyclic benzo[4,5]cyclohepta[1,2,3‐de]naphthalene core is also synthesized.
Keywords:Photolysis  Dibenzo[a,d]cycloheptene  Dimer
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