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Switchable Biosensor Controlled by Biocatalytic Process
Authors:Caroline R Basso  Bruna L Santos  Valber A Pedrosa
Institution:Institute of Bioscience, Department of Chemistry and Biochemistry, UNESP, Botucatu, SP‐Brazil
Abstract:The poly(dimethylamino methacrylate) (PDMAEMA) brush‐modified indium tin oxide (ITO) electrode was used to test the switch properties of interfacial activity caused by bioelectrochemical signals. The swelling of the polymer brushes increased when the medium’s pH changed from alkaline to acid after glucose was added to the system. A pH change generated in situ by means of biocatalytic reactions enabled bioelectrocatalytic interface’s reversible activation.
Keywords:Bioelectrocatalytic process  Biosensors  Polymer brushes
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