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Three New C19‐Diterpenoid Alkaloids from Aconitum forrestii
Authors:Jun‐Ju Xu  Da‐Ke Zhao  Hong‐Lian Ai  Li‐Mei Zhang  Shi‐Qing Xie  Shu‐Hui Zi  Sheng‐Chao Yang  Yong Shen
Affiliation:1. Yunnan Research Center on Good Agricultural Practice for Dominant Chinese Medicinal Materials, College of Agriculture and Biotechnology, Yunnan Agricultural University, Kunming 650201, P.?R. China;2. School of Agriculture, Yunnan University, Kunming 650091, P.?R. China, (phone:+86‐871‐65227213;3. fax:+86‐871‐65227213)
Abstract:A further study of the alkaloid constituents of Aconitum forrestii led to the isolation of three new C19‐diterpenoid alkaloids, named 14‐acetoxy‐8‐O‐methylsachaconitine ( 1 ), 14‐acetoxyscaconine ( 2 ), and 8‐O‐ethylcammaconine ( 3 ). Their structures were determined by UV, IR, and MS, 1D‐ and 2D‐NMR analyses.
Keywords:Aconitum forrestii  Alkaloids  Diterpenoid alkaloids  Sachaconitine, 14‐acetoxy‐8‐O‐methyl‐  Scaconine, 14‐acetoxy‐  Cammaconine, 8‐O‐ethyl‐
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