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Petrorhagiosides A – D,New γ‐Pyrone Derivatives from Petrorhagia saxifraga Link
Authors:Brigida D'Abrosca  Severina Pacifico  Monica Scognamiglio  Nikolaos Tsafantakis  Emanuela Pagliari  Pietro Monaco  Antonio Fiorentino
Institution:1. Department of Environmental, Biological and Pharmaceutical Sciences and Technologies, Phytochemistry Laboratory, Second University of Naples, via Vivaldi 43, I‐81100 Caserta, (phone: +39‐0823‐274576;2. fax: +39‐0823‐274571)
Abstract:Four novel γ‐pyrone (=4H‐pyran‐4‐one) metabolites, petrorhagiosides A–D, along with four known analogs, have been isolated from the MeOH extract of Petrorhagia saxifraga, a perennial herbaceous plant typical of Mediterranean vegetation. The structures of the new compounds were established on the basis of extensive spectroscopic analyses including 1D‐ an 2D‐NMR (1H,1H‐DQ‐COSY, TOCSY, HSQC, CIGAR‐HMBC, and HSQC‐TOCSY) experiments.
Keywords:Petrorhagia saxifraga  γ  ‐Pyrones  Petrorhagiosides A       D  Metabolites
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