Alkaloids from the Twigs and Leaves of Daphniphyllum macropodum |
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Authors: | Chuan‐Rui Zhang Hong‐Bing Liu Shi‐Hui Dong Yan Wu Jian‐Min Yue |
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Institution: | State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, 555 Zuchongzhi Road, Zhangjiang Hi‐Tech Park, Shanghai 201203, P.?R. China, (phone/fax: +86‐21‐50806718) |
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Abstract: | Three new alkaloids, macrodumines A–C ( 1 – 3 , resp.), along with ten known analogs, were isolated from the twigs and leaves of Daphniphyllum macropodum. Their structures were elucidated on the basis of spectroscopic methods. The 11‐OH configuration of the known alkaloid hydroxydaphgraciline ( 4 ) was assigned as α for the first time by comparing the NMR data with those of macrodumine C ( 3 ). |
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Keywords: | Daphniphyllum macropodum Alkaloids Macrodumines A – C |
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