Synthesis,Characterization and Properties of a Novel Environmentally Friendly Mono Azo Disperse Dye and Its Application on Polyethylene Terephthalate (PET) |
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| Authors: | Mohammad Dodangeh Mehrdad Mohammadian Norman S Allen Elmira Pajootan |
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| Institution: | 1. Young Researchers Club, Islamic Azad University, Kashan Branch, Kashan, Iran;2. Department of Textile Engineering, Islamic Azad University, Kashan Branch, Kashan, Iran;3. Department of Chemistry and Materials, Facuality of Science and Engineering, The Manchester Metropolitan University, Manchester, UK;4. Department of Textile Engineering, Amirkabir University of Technology, Tehran, Iran |
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| Abstract: | The aim of this research is to achieve the synthesis of a novel mono azo disperse dye containing both a β‐naphthyl acetate group and carboxylic acid ester group and application on PET fabric. In this study the dyeing properties have also been investigated. The synthesized dye was characterized using UV‐Vis, FTIR, 1H NMR and 13C NMR spectroscopic techniques. To investigate alkali‐clearability, both alkali‐hydrolysis behavior and the effect of its fastness properties with regard to PET fabric were examined. This dye showed a reasonable level of hydrolysis under relatively mild alkaline conditions. The application of the dye to PET fabric showed good leveling and building up properties. Estimating fastness properties of the dyed fabric showed excellent wash, rubbing fastness, good light and sublimation fastness. The results furthermore displayed that the synthesized dye offers the option of alkali‐clearing process over that of a conventional reduction‐clearing process. Therefore, the value of Chemical Oxygen Demand (COD), Biological Oxygen Demand (BOD) and water pollution as well as the expenditure of production were decreased. |
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| Keywords: | Alkali‐clearable azo disperse dye Carboxylic acid ester Polyethylene terephthalate Fastness properties Biuld‐up properties Chromatography |
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