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Copper‐Catalyzed One‐Pot Synthesis of N‐Sulfonylalkanimidoyl Thiocyanates from Sulfonyl Azides,Alkynes, and KSCN
Authors:Issa Yavari  Tahereh Damghani  Manijeh Nematpour
Institution:1. Department of Chemistry, Tarbiat Modares University, P.O. Box 14115‐175, Tehran, Iran, (phone: +98‐21‐82883465;2. fax: +98‐21‐82883455)
Abstract:Ketenimine intermediates generated by the addition of copper acetylides to sulfonyl azides are trapped by KSCN to afford N‐sulfonylalkanimidoyl thiocyanates in moderate‐to‐good yields.
Keywords:Copper iodide  Thiocyanates  Tosyl azide  Ketenimines  Alkynes  Catalysis  Multicomponent reactions
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