| 共反应剂TPPD的制备 |
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| 引用本文： | 冉红,梁艳霞,刘娟娟,肖丹. 共反应剂TPPD的制备[J]. 化学研究与应用, 2012, 24(9): 1453-1456 |
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| 作者姓名： | 冉红 梁艳霞 刘娟娟 肖丹 |
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| 作者单位： | 1. 四川大学化工工程学院,四川成都,610065
2. 四川大学化学学院,四川 成都,610064 |
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| 摘 要： | 本实验合成了一种共反应剂N,N,N’,N’-4-丙基-戊二胺(TPPD),它的分子中含有两个叔氨基,与传统的共反应剂三丙胺(TPA)相比增加了一个氮的活性位点。并且分子中的碳碳长链使得TPPD的疏水性增加,因此能与钌配合物[Ru(bpy)3][4-(Clph)4B]2同时固定到ITO电极上,减少了ECL过程中的共反应剂的消耗。
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| 关 键 词： | 共反应剂 合成 电致化学发光 |
Synthesis of a nevol co-reactant TPPD |
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| RAN Hong , LIANG Yan-xia , LIU Juan-juan , XIAN Dan. Synthesis of a nevol co-reactant TPPD[J]. Chemical Research and Application, 2012, 24(9): 1453-1456 |
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| Authors: | RAN Hong LIANG Yan-xia LIU Juan-juan XIAN Dan |
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| Affiliation: | RAN Hong1,LIANG Yan-xia1,LIU Juan-juan2,XIAN Dan1(1.College of Chemical Engineering,Sichuan University,Chengdu 610065,China; 2.College of Chemistry,Sichuan University,Chengdu 610064,China) |
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| Abstract: | In this work,a new organic-soluble co-reactant N,N,N’,N’-tetrakis(propyl)-pentanediamine(TPPD)was synthesized.It contains two tertiary amines.Compared with the traditional co-reactant,such as tripropylamine(TPA)it has two nitrogen active sites.The new co-reactant is very hydrophobic and thus could be co-immobilized with tris(2,2’-bipyridine)ruthenium(II)ditetrakis(4-chlorophenyl)borate[Ru(bpy)3][4-(Clph)4B]2 on an indium tin oxide(ITO)electrode.So the consumption of co-reactant is greatly reduced in the electrochemiluminescent(ECL)process. |
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| Keywords: | co-reactant synthesis electrochemiluminescent |
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