| Ni(C3H10N2)2NO2(ClO4)晶体的ESR研究 |
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| 引用本文： | 郭胜利. Ni(C3H10N2)2NO2(ClO4)晶体的ESR研究[J]. 波谱学杂志, 1999, 16(3): 181-186 |
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| 作者姓名： | 郭胜利 |
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| 作者单位： | 南京气象学院物理系, 南京 210044 |
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| 摘 要： | 报道了Ni(C3H10N2)2NO2(ClO4)晶体在T=1.5K温度和W波段的ESR实验.建立了d8离子基态3A2(F)的零场分裂参量D,E,和g因子与斜方对称晶场势参量间的关系,并应用于Ni(C3H10N2)2NO2(ClO4)晶体.计算值与实验数据符合很好,表明所给关系式是合理的.
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| 关 键 词： | 电子自旋共振(ESR) 零场分裂 Ni(C3H10N2)2NO2(ClO4)晶体 |
| 收稿时间： | 1999-01-25 |
ESR OF Ni(C3H10N2)2NO2(ClO4) CRYSTAL |
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| Guo Shengli. ESR OF Ni(C3H10N2)2NO2(ClO4) CRYSTAL[J]. Chinese Journal of Magnetic Resonance, 1999, 16(3): 181-186 |
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| Authors: | Guo Shengli |
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| Affiliation: | Physics Department, Nanjing Institute of Meteorology, Nanjing 210044 |
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| Abstract: | This paper reports experimental results of ESR for Ni(C 3H 10 N 2) 2NO 2(ClO 4) crystal at T =1.5K and 101GHz. We established a relationship between spin Hamiltonian parameters D,E,g factor and an orthorhombic symmetry crystalline potential components for a ground state 3A 2(F) of d 8 ions. The spin Hamiltonian parameters D, E and g factor of Ni(C 3H 10 N 2) 2NO 2(ClO 4) are calculated. The results agree well with the experimental findings, indicating that the given relationships are reasonable. |
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| Keywords: | ESR Zero field splitting Ni(C 3H 10 N 2) 2NO 2(ClO 4) |
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