Three-dimensional Potential Energy Surface and Bound States of the Ar2-Ne Complex |
| |
Authors: | Mei Niu Xiao-tao Xu Xia Chen Xiao-long Hu Xiao-long Hu |
| |
Affiliation: | Department of Physics, Anhui Normal University, Wuhu 241000, China |
| |
Abstract: | The first three-dimensional interaction potential energy surface (PES) of the Ar2-Ne complex is developed using the single and double excitation coupled cluster theory with noniterative treatment of triple excitations CCSD(T). The aug-cc-pVQZ basis sets are employed for all atoms, including an additional (3s3p2d2f1g) set of midpoint bond functions. The calculated single point energies are fitted to an analytic two-dimensional potential model at each of seven fixed rAr2 values. The seven model potentials are then used to construct the three-dimensional PES by interpolating along (r—re) using a sixth-order polynomial. The PES is used in the following rovibrational energy levels calculations. The comparisons of theoretical transition frequencies and spectroscopic constants with the experimental results are given. |
| |
Keywords: | Ar2-Ne complex Potential energy surface Rotational spectra |
|
| 点击此处可从《化学物理学报(中文版)》浏览原始摘要信息 |
|
点击此处可从《化学物理学报(中文版)》下载免费的PDF全文 |