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Structure of polymer fluids in colloidal dispersions
Affiliation:1. Air Force Research Laboratory, Materials and Manufacturing Directorate, Wright Patterson Air Force Base, OH 45433-7750, USA;2. Department of Materials and Interfaces, Weizmann Institute of Science, Rehovot 76100, Israel;1. Department of Chemical Engineering, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061-0211, USA;2. Department of Chemical Engineering, Kyungpook National University, Daegu 702-701, Republic of Korea
Abstract:We have calculated some structural properties of a fluid of hard sphere polymer chains about a variable sized central hard sphere with the Monte Carlo method in the canonical ensemble. We have additionally calculated these structural properties with an integral equation based on density functional theory. The integral equation theory gives good agreement with the simulations at all but the highest densities.
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