Hydrothermal Syntheses and Structural Characterization of One-Dimensional [Cu4Br2I3(C12H8N2)2]
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and Molecular Cu3Br3(C12H8N2)2 |
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| Authors: | Jie-Hui Yu Ji-Qing Xu Ling Ye Hong Ding Jia-Ning Xu Hong-Bin Jia Tie-Gang Wang Zhong-Cheng Mu Guang-Di Yang |
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| Institution: | (1) Department of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun Jinlin, 130023, People's Republic of China;(2) Key Laboratory of Supramolecular structure and Materials of Ministry of Education, Jilin University, Changchun Jinlin, 130023, People's Republic of China;(3) Department of Chemistry, Inner Mongolia University for Nationalities, People's Republic of China |
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| Abstract: | The hydrothermal reactions of CuBr2, CuX (X=Br, I), and phen (phen=1,10-phenanthroline, C12H8N2) have lead to the syntheses of two novel complexes of one-dimensional Cu4Br2I3(phen)2]
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1 and trinuclear discrete cluster Cu3Br3(phen)2
2. Both compounds were characterized by singe-crystal X-ray diffraction. Crystal data for 1. Monoclinic, space group P2
1/c with a=14.054(3) Å, b=13.700(3) Å, c=15.920(3) Å,  =114.16(3)°, Z=2; 2. Monoclinic, space group C2/c with a=10.040(2) Å, b=14.516(3) Å, c=16.319(3) Å, =94.29(3)°, Z=6. |
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| Keywords: | Hydrothermal synthesis crystal structure copper(I) halide 1 10-phenanthroline mixed valence |
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