| 铜铟铝硒硫薄膜的低成本非真空混合法制备 |
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| 引用本文： | 刘兆范,夏伟,袁晨辰,罗派峰.铜铟铝硒硫薄膜的低成本非真空混合法制备[J].化学物理学报,2015,28(6):746-750. |
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| 作者姓名： | 刘兆范 夏伟 袁晨辰 罗派峰 |
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| 作者单位： | 合肥工业大学材料科学与工程学院，合肥230009,合肥工业大学材料科学与工程学院，合肥230009,中国科学技术大学中国科学院能量转换材料重点实验室，合肥 230026,合肥工业大学材料科学与工程学院，合肥230009 |
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| 摘 要： | 采用溶剂热法制备出铜铟铝硒Cu(In,Al)Se2 (CIASe)粉末，然后滴涂铜铟铝硒CIASe浆料获得前驱体薄膜，最后通过硒化/硫化过程制备出铜铟铝硒CIASe和铜铟铝硒硫CIASeS薄膜．通过XRD、SEM、XRF及光吸收等表征，发现所制备的薄膜为单相的黄铜矿结构，具有(112)择优取向．同时，在使用硫元素替代硒之后，薄膜的XRD主峰向高的2θ角度漂移，多孔薄膜也变得更加致密．薄膜带隙值也增加到更为合适的范围，从1.21 eV增加到1.33 eV，这也说明了硫化过程有利于提高CIASeS薄膜的质量．
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| 关 键 词： | 溶剂热法，非真空，硫化 |
| 收稿时间： | 2/3/2015 12:00:00 AM |
Preparation of Cu(In,Al)(Se,S)2 Thin Films by Low-Cost Non-vacuum Hybrid Process |
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| Zhao-fan Liu,Wei Xi,Chen-chen Yuan and Pai-feng Luo.Preparation of Cu(In,Al)(Se,S)2 Thin Films by Low-Cost Non-vacuum Hybrid Process[J].Chinese Journal of Chemical Physics,2015,28(6):746-750. |
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| Authors: | Zhao-fan Liu Wei Xi Chen-chen Yuan and Pai-feng Luo |
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| Institution: | Department of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China,Department of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China,CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei 230026, China and Department of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China |
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| Abstract: | |
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| Keywords: | Non-vacuum Solvothermal X-ray diffraction Sulfuration |
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