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Reactions of Elemental Phosphorus with Electrophiles in Super Basic Systems: XVII. Phosphorylation of Arylalkenes with Active Modifications of Elemental Phosphorus |
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| Authors: | B. A. Trofimov N. K. Gusarova S. F. Malysheva V. A. Kuimov B. G. Sukhov S. I. Shaikhudinova N. P. Tarasova Yu. V. Smetannikov O. G. Sinyashin Yu. G. Budnikova T. I. Kazantseva V. I. Smirnov |
| Affiliation: | (1) Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia;(2) Mendeleev Russian University of Chemical Technology, Moscow, Russia;(3) Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia |
| Abstract: | The example of the phosphorylation of styrene and 2-vinylnaphthalene with elemental phosphorus in the KOH-DMSO system at room or elevated temperature was used to show that the activated red phosphorus prepared from white phosphorus under ionizing radiation has a reactivity comparable with that of white phosphorus and significantly higher than that of ordinary technical red phosphorus. |
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