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Reactions of 2-methylene-3-oxoquinuclidine with carbonyl compounds |
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| Authors: | V. A. Bondarenko E. E. Mikhlina T. Ya. Filipenko K. F. Turchin Yu. N. Sheinker L. N. Yakhontov |
| Affiliation: | (1) S. Ordzhonikidze All-Union Scientific-Research Institute of Pharmaceutical Chemistry, 119021 Moscow |
| Abstract: | The reaction of 2-methylene3-oxoquinuclidine with ketones,  -diketones, keto esters, and cyano esters was studied. Products of mono- and diaddition of the unsaturated ketone are formed in the presence of catalytic or equimolar amounts of sodium ethoxide, as well as without a catalyst (in the case of -keto esters and -diketones).Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1387–1391, October, 1981. |
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