| 手性有机磷化合物液相拆分的研究进展 |
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| 引用本文： | 周爱玲,吕宪禹,黄君珉,王新省,高如瑜. 手性有机磷化合物液相拆分的研究进展[J]. 色谱, 2002, 20(6): 502-507 |
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| 作者姓名： | 周爱玲 吕宪禹 黄君珉 王新省 高如瑜 |
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| 作者单位： | 1. 南开大学化学学院,天津,300071
2. 南开大学生命科学学院,天津,300071 |
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| 摘 要： | 综述了近年来手性有机磷化合物液相拆分的研究进展。对间接拆分和直接拆分法,特别是各类手性固定相法在拆分有机磷化合物中的应用作了介绍,探讨了相应的拆分机理。85篇。
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| 关 键 词： | 液相 手性固定相 有机磷化合物 手性拆分 |
| 文章编号： | 1000-8713(2002)06-0502-06 |
| 修稿时间： | 2002-03-14 |
Advances in the Chiral Resolution of Organophosphorus Compounds by Liquid Chromatography |
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| Ai-ling Zhou,Xian-yu Lü,Jun-min Huang,Xin-sheng Wang,Ru-yu Gao. Advances in the Chiral Resolution of Organophosphorus Compounds by Liquid Chromatography[J]. Chinese journal of chromatography, 2002, 20(6): 502-507 |
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| Authors: | Ai-ling Zhou Xian-yu Lü Jun-min Huang Xin-sheng Wang Ru-yu Gao |
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| Affiliation: | College of Chemistry, Nankai University, Tianjin 300071, China. zhouailing@eyou.com |
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| Abstract: | The developments in the chiral resolution of organophosphorus compounds by liquid chromatography in recent years are reviewed. Two different approaches of separation: indirect resolution (chiral derivatization reagent method) and direct resolution (chiral mobile phase additive and chiral stationary phase), focusing on several chiral stationary phases--Pirkle type, cyclodextrin, cellulose, ligand exchange and other chiral stationary phases are presented. The possible mechanism of chiral recognition is discussed. Eighty-five references are involved. |
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| Keywords: | liquid chromatography chiral stationary phase organophosphorus compound chiral resolution |
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